非制冷热释电薄膜红外探测器热绝缘结构的研制

采用由多孔SiO2薄膜和过渡SiO2薄膜组成的复合薄膜结构实现了非制冷热释电薄膜红外探测器的热绝缘.利用溶胶凝胶方法制备了多孔SiO2薄膜以及过渡SiO2薄膜,通过优化制备工艺,使得多孔SiO2一次成膜厚度达到3070nm,孔率达到59%;过渡SiO2一次成膜的厚度达到188nm,孔率达到4%.AFM表明,由过渡SiO2薄膜与多孔SiO2组成的复合薄膜结构的表面粗糙度远小于多孔SiO2薄膜的表面粗糙度.该热绝缘结构有利于探测器后续各层功能薄膜的集成.     

LPCVD制备二氧化硅薄膜工艺研究

采用TEOS源LPCVD法制备了SiO2薄膜,采用膜厚仪对薄膜的厚度进行测试.通过不同条件下SiO2薄膜的厚度变化,讨论了TEOS源温度、反应压力及反应温度等工艺条件对淀积速率和均匀性的影响.结果表明,在40℃,50 Pa左右,淀积速率随TEOS源温度、反应压力基本呈线性增大.通过多次试验改进,提出了SiO2膜淀积的典...     

脉冲激光溅射沉积光学增益薄膜实验研究

用脉冲激光沉积方法,以多靶交替溅射方式,在SiO2/Si基底上沉积镱铒共掺Al2O3光学薄膜,讨论了脉冲激光能量对薄膜沉积速率、表面形貌、光致发光强度的影响.在脉冲激光能量较高条件下制备出的薄膜的光致发光性能较好,脉冲激光能量较低条件下制备出的薄膜的表面形貌较均匀.综合放大器增益系数对光致发光强度和光刻工艺对薄膜表面形貌的要求,薄膜应该在合适的激光能量下制备.脉冲激光溅射沉积方法与中频磁控溅射方法相比,在抑制上转换发光方面具有优越性.     

PECVD SiO2 薄膜内应力研究

研究了等离子体增强化学气相淀积(PWCVD)法生长SiO2薄膜的内应力.借助XP-2型台阶仪和椭偏仪测量计算了SiO2薄膜的内应力,通过改变薄膜淀积时的工艺条件,如淀积温度、气体流量、反应功率、腔体压力等,分析了这些参数对SiO2薄膜内应力的影响.同时讨论了内应力产生的原因以及随工艺条件变化的机理,对工艺条件的优化有一定参考价值.     

应用于FRAM的集成铁电电容的研究

集成铁电电容的制备是铁电存储器的关键工艺之一。该文采用射频(RF)磁控溅射法在Pt/Ti/SiO2/Si制备Pb(Zr,Ti)O3(PZT)薄膜,上下电极Pt采用剥离技术工艺制备,刻蚀PZT薄膜,形成Pt/PZT/Pt/Ti/SiO2/Si集成电容结构,最后高温快速退火。结果表明,这种工艺条件可制备性能良好的铁电电容,符合铁电存储器对铁电电容的要求。     

PECVD法制备SiO2膜均匀性研究

针对半导体产业对氧化硅薄膜的需求,介绍了采用自制的PECVD设备研究了SiO2薄膜生长的膜厚均匀性分别与喷淋板孔结构和工艺参数之间的关系。实验结果表明:在结构方面,SiO2薄膜均匀性主要受到喷淋板孔径大小与结构的影响;在工艺参数方面,SiO2薄膜的膜厚均匀性主要受到反应腔室压力的影响。通过结构和工艺参数的综合调整,制备出了膜厚均匀性好的SiO2薄膜。     

纳米压痕和划痕法测定氧化硅薄膜材料的力学特性

为了研究不同制备工艺对材料力学性能的影响,选择了热氧化、LPCVD和PECVD三种典型工艺,在硅片上制备1μm氧化硅薄膜.通过纳米压痕和划痕检测可知,热氧化工艺制备的SiO2薄膜的硬度和模量最大,LPCVD制备的样品界面结合强度高于PECVD.纳米压痕和划痕技术为此提供了丰富的近表面弹塑性变形和断裂等的信息,是评价微米薄膜力学性能的有效手段.     

PSTM 用于Al_2O_3光波导薄膜的研究

利用光子扫描隧道显微镜 (PSTM)检测研究 Al2 O3光波导薄膜及其制备工艺。分析了不同温度条件下采用离子束增强沉积工艺制备的 Al2 O3光波导薄膜 PSTM图像。结果表明 :适当的增加基片的温度可以减小散射损耗 ,改善 Al2 O3光波导薄膜的性能     

利用光子晶体提高InP基LED出光效率

应用FDTD方法计算了二维无限大光子晶体的能带结构,并制备出了InP基二维平板结构的光子晶体器件.在制备过程中尝试了仅用PMMA做掩模以及PMMA和SiO2做掩模两种方法.结果表明,不使用SiO2做掩模的情况下,由于PMMA胶选择性较差,在刻蚀过程中难以保证图形的准确转移.而增加SiO2掩模后,获得了图形质量良好的光子晶体结构.成功实现了利用光子晶体结构增强LED的出光效率,与未制作光子晶体结构的LED相比,光子晶体结构LED的出光效率可在原来基础上提高1倍以上.并且随着晶格常数的增加,出光效率进一步提高.     

利用光子晶体提高InP基LED出光效率

应用FDTD方法计算了二维无限大光子晶体的能带结构,并制备出了InP基二维平板结构的光子晶体器件.在制备过程中尝试了仅用PMMA做掩模以及PMMA和SiO2做掩模两种方法.结果表明,不使用SiO2做掩模的情况下,由于PMMA胶选择性较差,在刻蚀过程中难以保证图形的准确转移.而增加SiO2掩模后,获得了图形质量良好的光子晶体结构.成功实现了利用光子晶体结构增强LED的出光效率,与未制作光子晶体结构的LED相比,光子晶体结构LED的出光效率可在原来基础上提高1倍以上.并且随着晶格常数的增加,出光效率进一步提高.     

Preparation and Characterization of TaN ALD Precursors

High purity organic-tantalum precursors for thin film ALD TaN were synthesized and characterized.Vapor pressure and thermal stability of these precursors were studied.From the vapor pressure analysis,it was found that TBTEMT has a higher vapor pressure than any other published liquid TaN precursor,including TBTDET,TAITMATA,and IPTDET.Thermal stability of the alkyl groups on the precursors was investigated using a 1H NMR technique.The results indicated that the tertbutylimino group is the most stable group on TBTDET and TBTEMT as compared to the dialkylamido groups.Thermal stability of TaN precursors decreased in the following order:TBTDET ＞ PDMAT ＞ TBTEMT.In conclusion,precursor vapor pressure and thermal stability were tuned by making slight variations in the ligand sphere around the metal center.     

Curved crystal spectrometer for the measurement of X-ray lines from laser-produced plasmas

In order to diagnose the laser-produced plasmas, a focusing curved crystal spectrometer has been developed for measuring the X-ray lines radiated from a laser-produced plasmas. The design is based on the fact that the ray emitted from a source located at one focus of an ellipse will converge on the other focus by the reflection of the elliptical surface. The focal length and the eccentricity of the ellipse are 1350 mm and 0.9586, respectively. The spectrometer can be used to measure the X- ray lines in the wavelength range of 0.2-0.37 nm, and a LiF crystal （200） （2d = 0.4027 nm） is used as dispersive element covering Bragg angle from 30° to 67.5°. The spectrometer was tested on Shengnang- Ⅱ which can deliver laser energy of 60-80 J/pulse and the laser wavelength is 0.35 μm. Photographs of spectra including the 1 s2p ^1P1-1s^2 ^1S0 resonance line（w）, the 1s2p ^3P2-1s^2 1S0 magnetic quadrupole line（x）, the 1s2p ^3P1-1 s^2 ^1S0 intercombination lines（y）, the 1 s2p ^3S~1-1 s^2 ^1S0 forbidden line（z） in helium-like Ti Ⅹ Ⅺ and the 1 s2s2p ^2P3/2-1 s622s ^2S1/2 line（q） in lithium-like Ti Ⅹ Ⅹhave been recorded with a X-ray CCD camera. The experimental result shows that the wavelength resolution（λ/△ 2） is above 1000 and the elliptical crystal spectrometer is suitable for X-ray spectroscopy.     

Electronic Structure of Semiconductor Nanocrystals

This paper reviews our recent development of the use of the large-scale pseudopotential method to calculate the electronic structure of semiconductor nanocrystals, such as quantum dots and wires, which often contain tens of thousands of atoms. The calculated size-dependent exciton energies and absorption spectra of quantum dots and wires are in good agreement with experiments. We show that the electronic structure of a nanocrystal can be tuned not only by its size,but also by its shape. Finally,we show that defect properties in quantum dots can be significantly different from those in bulk semiconductors.     

Critical Stage Rule-Based Real Time Dispatch（RTD）System in Highly-Mixed-Products （HMP） FAB

An improving utilization and efficiency of critical equipments in semiconductor wafer fabrication facilities are concerned. Semiconductor manufacturing FAB is one of the most complicated and cost sensitive environments. A good dispatching tool will make big difference in equipment utilization and FAB output as a whole. The equipment in this paper is In-Line DUV Scanner. There are many factors impacting utilization and output on this equipment group. In HMP environment one of the issues is changing of reticule in this area and idle counts due to load unbalance between equipments. Here we'll introduce a rule-based RTD system which aiming at decreasing the number of recipe change and idle counts among a group of scanner equipment in a high-mixed-products FAB.     

GaAsSb/InAlAs PA DHBTs Grown by Production MBE

The epi material growth of GaAsSb based DHBTs with InAlAs emitters are investigated using a 4 × 100mm multi-wafer production Riber 49 MBE reactor fully equipped with real-time in-situ sensors including an absorption band edge spectroscope and an optical-based flux monitor. The state-of-the-art hole mobilities are obtained from 100nm thick carbon-doped GaAsSb. A Sb composition variation of less than ± 0.1 atomic percent across a 4 × 100mm platen configuration has been achieved. The large area InAlAs/GaAsSb/InP DHBT device demonstrates excellent DC characteristics,such as BVCEO＞6V and a DC current gain of 45 at 1kA/cm2 for an emitter size of 50μm × 50μm. The devices have a 40nm thick GaAsSb base with p-doping of 4. 5 × 1019cm-3 . Devices with an emitter size of 4μm × 30μm have a current gain variation less than 2% across the fully processed 100mm wafer. ft and fmax are over 50GHz,with a power efficiency of 50% ,which are comparable to standard power GaAs HBT results. These results demonstrate the potential application of GaAsSb/InP DHBT for power amplifiers and the feasibility of multi-wafer MBE for mass production of GaAsSb-based HBTs.     

Technology innovation and process integrations for sub-100nm gate patterning

This paper presents a brief overview of the Applied Centura(R)DPS(R)system,configured with silicon etch DPS Ⅱ chamber, with emphasis on discussing tuning capability for CD uniformity control. It also presents the studies of etch process chemistry and film integration impact for an overall successful gate patterning development. Discussions will focus on resolutions to key issues, such as CD uniformity, line-edge roughness, and multilayer film etching integration.     

White organic light-emitting devices based on fac tris（2- phenylpyridine） iridium sensitized 5,6,11,12-tetraphenylnap -hthacene

We have fabricated the white organic light-emitting devices （WOLEDs） based on 4,4＇ -bis（2,2 -diphenyl vinyl）-1,1＇ - biphenyl （DPVBi） and phosphorescence sensitized 5,6,11,12,-tetraphenylnaphthacene （rubrene）. The device structure is ITO/2T-NATA （20 nm）/NPBX （20 nm）/CBP： x%Ir（ppy）3：0.5% rubrene （8 nm）/NPBX （5 nm）/DPVBi （30 nm）/Alq（30 nm）/LiF（0.5 nm）/A1. In the devices, DPVBi acts as a blue light-emitting layer, the rubrene is sensitized by a phosphorescent material, fac tris （2-phenylpyridine） iridium [Ir（ppy）3], acts as a yellow light-emitting layer, and N,N＇ -bis- （1-naphthyl）- N,N＇ -diphenyl -1, 1＇ -biphenyl-4,4＇ -diamine （NPBX） acts as a hole transporting and exciton blocker layer, respectively. When the concentration of Ir （PPY）3 is 6wt%, the maximum luminance is 24960 cd/m^2 at an applied voltage of 15 V, and the maximum luminous efficiency is 5.17 cd/A at an applied voltage of 8 V.     

Complete approach to automatic identification and subpixel center location for ellipse feature

To meet the need of automatic image features extraction with high precision in visual inspection, a complete approach to automatic identification and sub-pixel center location for similar-ellipse feature is proposed. In the method, the feature area is identified automatically based on the edge attribute, and the sub-pixel center location is accomplished with the leastsquare algorithm. It shows that the method is valid, practical, and has high precision by experiment. Meanwhile this method can meet the need of instrumentation of visual inspection because of easy realization and without man-machine interaction.     

小角度扩展相关性近似算法分析

本论文提出一种在多天线MIMO信道相关性建模中小角度扩展近似理论算法,并应用于分析MIMO系统性能。分析中分别对三种不同角能量分布情况下的空间相关性研发快速近似计算法,并同时提出双模(Bi-Modal)角能量分布情况下的近似运算。通过分析这些新方法的近似效率,可以得到计算简单、复杂度低、而且符合实际的MIMO相关信道矩阵,对系统级的快速高效计算法的研究和系统级的评估以及误差分析具有重要的意义。     

Noise character analysis and the restraint of self-pulsation laser diodes

We calculate the Langevin noise sources of self-pulsation laser diodes, analyze the effects of active region noise and saturable-absorption region noise on the power fluctuation as well as period fluctuation, and propose a novel method to restrain the noise effects. A visible SIMULINK model is established to simulate the system, The results indicate that the effects of noise in absorption region can be ignored; that with the increase of DC injecting current, the noise effects enhance power jitter, and nevertheless, the period jitter is decreased; and that with external sinusoidal current modulating the self-pulsation laser diode, the noise-induced power jitter and period jitter can be suppressed greatly. This work is valuable for clock recovery in all-optical network.