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镁合金表面铈多层膜的抗腐蚀性及细胞相容性研究 总被引:2,自引:0,他引:2
利用旋转涂布法在镁合金表面构建了由聚乙烯亚胺(Polyethyleneimine,PEI)、明胶(Gelatin,Gel)和硝酸铈(Cerium nitrate)组成的抗腐蚀性铈多层膜.采用接触角测试仪表征了铈多层膜在镁合金表面的组装过程;利用电化学交流阻抗图谱和极化曲线研究了铈多层膜修饰的镁合金在0.14mol/L NaCl溶液中的抗腐蚀性能;以MTT和碱性磷酸酶考察了铈多层膜修饰镁合金的细胞相容性.结果表明,在镁合金表面形成了铈多层膜结构,铈多层膜表面处理提高了镁合金的抗腐蚀性能和细胞相容性.该表面处理为镁合金植入体的应用提供了新思路. 相似文献
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常用的镁合金电镀前预处理时需预镀锌、预镀铜,还需使用氰化物,不仅污染环境,且预处理工艺复杂.为此,研究了AZ91D镁合金焦磷酸盐体系电镀铜的前处理工艺.分析了酸洗、活化、浸锌液主盐、配位剂、浸锌温度、浸锌时间等工艺参数对浸锌层质量的影响,确定了前处理工艺的优化条件.采用增重法测试了浸锌层的膜重,用电化学方法研究了镁合金的浸锌过程及浸锌层的耐蚀性能,用划痕、热震和锉刀法测试了经该前处理后所得镀铜层与基体的结合力.结果表明:采用该工艺电镀铜所得镀层细致、光亮,镀层与基体结合力良好,对镁合金基体有较好的防护作用. 相似文献
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表面强化、耐蚀处理对镁及其合金的应用至关重要。采用阴极多弧离子镀膜技术,在AZ91C镁合金基底上首次成功镀制了强结合力的以Ti为过渡层的TiN复合膜层,并利用高分辨扫描电子显微镜(SEM)、X射线能谱仪(EDS)、CSM显微划痕测试等技术对复合膜层的形貌、组织结构及性能进行分析研究。结果表明,采用适当的多弧离子镀膜工艺,能在经恰当预处理方法处理的镁舍金基底上制备性能良好的TiN膜。膜层均匀、致密,膜基结合力达130mN以上,复合硬度达500HV左右(AZ91镁合金基底125HV)。此外中性盐雾强化实验表明,经该方法处理后的镁合金在ASTM-B117标准测试条件下,腐蚀速度明显降低,经过200h后,表面无明显腐蚀现象。真空多弧离子镀膜技术有望在镁合金表面防护领域得到应用。 相似文献
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Bala T Joshi B Iyer N Sastry M Prasad BL 《Journal of nanoscience and nanotechnology》2006,6(12):3736-3745
Development of simple and efficient protocol for the synthesis of Ni nanoparticles in aqueous media and their subsequent phase transfer to organic media is reported. The synthesis of nickel nanoparticles in aqueous medium is accomplished by reducing the nickel nitrate with sodium borohydride in presence of oleic acid. It results in the formation of nickel nanoparticles capped with oleic acid. The pristine oleic acid capped nickel nanoparticles were then phase transferred to nonpolar solvents such as toluene using stearic acid. The phase transfer was effective probably due to the space exchange between the oleic acid moiety and stearic acid molecules. The hydrophobized Ni thus obtained was organized at the air-water interface and it was observed that by controlling the pressure and concentration of hydrophobized Ni nanoparticles at air-water interface, linear ribbon like assemblies could be obtained. The organization process was followed by surface pressure-area isotherm measurement and Brewster Angle Microscopy. 相似文献
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Integrated biological processes involving the dissolution and subsequent precipitation have been used for the treatment of the spent material from the hydrogenation of vegetable oil containing a high-level of nickel. Our results show that nickel was successfully leached using Acidithiobacillus thiooxidans. The percentages of nickel leached using A. thiooxidans were higher than those obtained with dilute sulphuric acid solutions. Due to the physical characteristics of the residue, the best results were obtained when the leaching process was carried out using sulphuric acid biogenerated by an A. thiooxidans biofilm. The recovery of nickel from the leachates was performed at room temperature by precipitating with sulphide generated by Desulfovibrio cells. Indirect precipitation using sulphide generated in Desulfovibrio sp. cultures allowed the recovery of nickel as the very insoluble nickel sulphide. 相似文献
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Wenchao Zhang Bo Xu Lianwei Wang Xiaowei Wang Jason A. Thomas Yimin Chao 《Journal of Materials Science》2013,48(23):8302-8307
Micro-energetic devices with energetic and functional diversity have attracted interest from scientific communities, through features such as the integration of energetic materials into micro-electro-mechanical systems (MEMS). In this study, a method for the preparation of nickel picrate energetic films on the sidewalls of a silicon microchannel plate (Si-MCP) is presented. The Si-MCP was produced by a photoelectrochemical process and a thin film of nickel (Ni) was synthesized by electroless plating of Ni on the sidewalls of the Si-MCP. The thin film of nickel picrate was successfully produced via an in situ chemical reaction method by introducing picric acid into the 3D ordered nickel/silicon microchannel plate (Ni/Si-MCP). Field emission scanning electron microscopy, Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy were used to study the morphological and structural properties of the thin film. The results demonstrate that picric acid reacted with Ni to form a nickel picrate thin film. Also, differential scanning calorimetry and thermogravimetric analysis were employed to characterize the thermal decomposition of the energetic film. The approach can solve the problem of integrating organic energetic materials with MEMS devices. Also, nickel picrate can release a mass of energy and gas simultaneously, which further enhances the functional diversity of MEMS devices. 相似文献
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本文对微波消解-原子吸收分光光度法测定土壤样品中的镍元素的分析方法进行了探讨,并对不同类型土壤消解后赶酸与不赶酸的测定结果进行了比较。结果表明,原子吸收法测定土壤中的镍必须赶酸,但赶酸的方法可以简化,并利用连续光源原子吸收光谱图进行了验证。 相似文献
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采用紫外分光光度法研究了丁炔二醇和丙炔醇在光亮镀镍过程中的阳极氧化反应,以期进一步认识添加剂在电镀过程中的作用机理.结果表明,炔醇类化合物在阳极生成了相应的有共轭体系的炔醛类和炔酸类化合物,产生了紫外吸收.当镍阳极处于钝化状态时阳极上有氯气产生,炔醇类氧化物的生成速度较快.选择活性镍作为光亮镀镍阳极,可以减少炔醇类光亮剂的氧化. 相似文献
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J. Vehlow 《Materialwissenschaft und Werkstofftechnik》1983,14(3):85-90
Investigations Into the Corrosion of Three Steels and one Nickel Alloy in Mono- and Trichloroacetic Acid The corrosion resistance of three steels and one nickel alloy was investigated in aqueous and nonaqueous monochloroacetic acid and in nonaqueous trichloroacetic acid at various temperatures. There is no difference in the corrosion behaviour of the steels whereas the resistance of the nickel alloy is better in all cases by a factor 10. In aqueous monochloroacetic acid the corrosion attack is due to the hydrolytic formation of hydrochloric acid. Nonaqueous monochloroacetic acid behaves more corrosive than nonaqueous trichloroacetic acid. 相似文献
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《Materials Science & Technology》2013,29(9):836-843
AbstractThe electrodeposition of nickel from nickel acetate dissolved in pure formamide was carried out and the effect of pH, current density, temperature, and boric acid concentration was studied. The temperature range of 40–50°C was found to be the best operating parameter at which usually bright and hard deposits having high cathode current efficiencies were obtained. A concentration of 0·1M boric acid in conjunction with 0·2M ammonium acetate resulted in deposits having exceptionally high levels of hardness. Variation of pH by hydrochloric acid led to bright, fine grained hard deposits, while changing pH by acetic acid possessing bulkier acetate ions resulted in soft and thin electrodeposits. Scanning electron microscopy revealed refinement in grain size with increasing temperature. A definite change in microstructure occurred when nickel electroplates were annealed to 400–600°C for 1 h and cooled slowly under atmospheric pressure.MST/746 相似文献
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《Materials Letters》2007,61(8-9):1615-1618
NiO nanoparticles have been successfully prepared by calcining malate gel, using basic nickel carbonate (BNC) and malic acid as the raw materials and H2O as the solvent. The reaction was studied by TG–DTA, XRD and FT-IR. The particle size and morphology of NiO nanoparticles was characterized by TEM. The results show that nickel malate could be formed by the reaction of BNC and malic acid; the gel was composed of nickel malate and residual malic acid; the precursor can translate into NiO nanoparticles completely at 400 °C under the air, and the as-prepared sample has a cubic crystal structure with about 14 nm of average diameter by the Scherrer formula. The NiO calcined at 400 °C for 1 h was of narrow particle size distribution, weak agglomeration and small particle size. The particle size of NiO increased with the increase in temperature. Compared with other methods, the developed method is simple and the raw materials were inexpensive, so that it has the potential for further scale-up application in the industry. Furthermore, the reason for the metallic nickel formation in the course of the preparation was explained. 相似文献
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This study examined the recovery of nickel and cobalt from organic acid complexes using a chelating aminophosphonate Purolite S950 resin. These metal complexes are generated by bioleaching nickel laterite ores, a commercial nickel and cobalt mineral oxide, with heterotrophic organism and their metabolites or organic acid products. Equilibrium adsorption tests were conducted as a function of Ni and Co concentrations (15-2000 mg/L), solution pH (0.01 and 0.1 M acids) and three metabolic complexing agents (citrate, malate and lactate). It was shown that the adsorption of the various Ni- and Co-complexes on Purolite were quite low, 16-18 and 5.4-9 mg/g of resin, respectively, in comparison to the smaller nickel ions and nickel sulfate. This was attributed to the bulky organic ligands which promoted crowding effect or steric hindrance. The adsorption of these complexes was further hampered by the strong affinity of the resin to H+ ions under acidic conditions. Mechanisms of adsorption, as inferred from the fitted empirical Langmuir and Freundlich models, were correlated to the proposed steric hindrance and competitive adsorption effects. Nickel and cobalt elution from the resin were found be effective and were independent of the type of metal complexes and metal concentrations. This study demonstrated the relative challenges involved in recovering nickel and cobalt from bioleaching solutions. 相似文献