Conductivité électrique totale du systeme iodure d'argent-diiodure de diazonia-6,9-dispiro[5.2.5.3]heptadecane

Résumé La réaction entre l'homopipérazine, HN<(CH₂)₅>NH, et le dibromo-1,5-pentane, Br(CH₂)₅Br, conduit à la formation du dibromure de diazonia-6,9-dispiro[5.2.5.3]heptadécane de formule C₁₅H₃₀N ₂ ²⁺ ·2Br^–. Par permutation en milieu aqueux ou organique on obtient le sel iodé. Ce diiodure est associé à l'iodure d'argent dans des proportions variant entre 75 et 95% en équivalent de AgI. L'étude de la conductivité électrique totale de ce système en fonction de la température montre que le sel double renfermant 82,5% en équivalent de AgI présente, à 25°C, une conductivité électrique totale de 0,0083 ( cm)^–1.

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The reaction between homopiperazine, HN<(CH₂)₅>NH, and dibromo-1,5-pentane, Br(CH₂)₅Br, gives a diazonia-6,9-dispiro[5.2.5.3]heptadecane dibromide, C₁₅H₃₀N ₂ ²⁺ ·2Br^–. This salt is iodized by permutation in aqueous or organic solution. This diiodide is associated with silver iodide in proportions varying between 75 and 95% equivalent silver iodide. The study of the total electric conductivity shows that the double salt, containing 82.5% equivalent silver iodide, gives a conductivity of 0.0083 ( cm)^–1 at 25°C.

     

两株抗氧化活性酵母的鉴定及对乳成分的影响

为获得有抗氧化活性的工业用酵母菌株,对2株来源于原料乳中有较强抗氧化活性的酵母菌进行鉴定.根据菌株的表型、生理生化特征和基因型的特性,初步将这2株菌鉴定为毕赤氏发酵酵母(Pichia fermentans).将这2株酵母菌在高温灭菌(UHT)牛乳中培养以研究其对牛乳主要成分的影响,结果表明:这2株酵母能在UHT牛乳中产乙醇,具有促进蛋白水解活性与脂肪水解活性的能力,能有效提高乳中的游离氨基酸和脂肪酸的含量.     

THE SINGLE PELLET DIFFUSION REACTOR: THEORY AND APPLICATIONS

Most heterogeneous catalysts are either supported on some kind of porous material or the catalyst itself is porous. To satisfy practical constraints such as pressure drop, handling, and separation from products, these catalysts are generally pelletized. Very often the overall chemical reaction rates within these catalyst pellets are determined by a complicated interaction of internal and external transport effects with the intrinsic kinetic rate at the active surface.     

The time dependent strain potential function for a polymeric glass

Torsion and normal force measurements were made during single step stress relaxation experiments on a polymeric glass (PMMA). Isochronal data were analysed using an approach adapted from that developed by Penn and Kearsley¹ (for incompressible elastic materials) to determine the derivatives $\text{?W}\text{?I}{}_1$, and $\text{?W}\text{?I}{}_2$ of the time dependent strain potential function. $\text{?W}\text{?I}{}_1$ and $\text{?W}\text{?I}{}_2$ are determined from existing solution to the torsion of an incompressible cylinder. A special solution to the torsion of a compressible cylinder is presented and it is shown that the values of $\text{?W}\text{?I}{}_1$ and $\text{?W}\text{?I}{}_2$ obtained using this solution to analyse the data do not differ greatly from those obtained using the incompressible solution. It is found from both solutions that $\text{?W}\text{?I}{}_1$ is negative and increases towards zero with increasing time and deformation while $\text{?W}\text{?I}{}_2$ is positive, greater in magnitude than $\text{?W}\text{?I}{}_1$ and decreases towards zero with increasing time and deformation. These results were unexpected and a full understanding of their meaning has yet to be reached.     

Effect of Microstructure on the Tribological and Mechanical Properties of CuO-Doped 3Y-TZP Ceramics

Dense 8 mol% CuO-doped 3Y-TZP ceramics were prepared by pressureless sintering for 8 h at 1500° and 1550°C, respectively. Transmission electron spectroscopy revealed that the ceramic sintered at 1500°C exhibits grain boundaries free of any amorphous phase, while crystalline copper-oxide grains were found in the zirconia matrix, whereas the sample sintered at 1550°C contains a Cu-rich amorphous grain boundary layer. The tribological behavior of these materials was tested under dry-sliding conditions using a pin-on-disk tribometer. The material sintered at 1500°C showed self-lubrication resulting in a low coefficient of friction ( f ) of 0.2–0.3 and a low specific wear rate ( k ) ≪ 10⁻⁶ mm³·(N·m)⁻¹. In contrast, the material sintered at 1550°C showed poor tribological behavior ( f =0.8–0.9; k ≫ 10⁻⁶ mm³·(N·m)⁻¹ under the same conditions. The difference in the tribological behavior of these two materials was interpreted on the basis of mechanical properties and microstructural characteristics.     

Air impingement and intermittent drying: Application to apple and to mango

An original drying process combining air impingement and intermittent drying was studied on apple slices and mango cubes. The influence of four operating parameters (air velocity, drying/tempering periods, upper height, and air temperature) on the drying time and on the drying rate was evaluated. Continuous and intermittent drying were compared. The intermittency α = 1/7 (τ_on = 10 seconds and τ_off = 60 seconds) gave the best results. A time savings of 54% for apple and 67% for mango was reached. In continuous drying, a time savings of 4620 seconds was observed by increasing the air velocity from 6 to 40 m s^?1 for apple. Air temperatures of 328 K for apple and of 328 K or 338 K for mango were determined as optimum to prevent case‐hardening. Experimental results were fitted with the analytical solution of Fick's second law and the modified Page equation (average values R² = 0.985 and 0.961, for apple and mango, respectively). For both products, the apparent moisture diffusivity D_app, the drying constant k, the drying coefficient n, and the activation energy E_a, were identified. Activation energies calculated from the analytical solution were 30.3 and 36.8 kJ mol^?1 and were 25.4 and 30.0 kJ mol^?1 using the modified Page equation for apple and mango, respectively. Mango has an increased temperature sensitivity and thus will need less energy for drying than apple.     

Comparing the Performance of Organic Solvent Nanofiltration Membranes in Non-Polar Solvents

Organic solvent nanofiltration (OSN) is gradually expanding from academic research to industrial implementation. The need for membranes with low and sharp molecular weight cutoffs that are able to operate under aggressive OSN conditions is increasing. However, the lack of comparable and uniform performance data frustrates the screening and membrane selection for processes. Here, a collaboration is presented between several academic and industrial partners analyzing the separation performance of 10 different membranes using three model process mixtures. Membrane materials range from classic polymeric and thin film composites (TFCs) to hybrid ceramic types. The model solutions were chosen to mimic cases relevant to today's industrial use: relatively low molar mass solutes (330–550 Da) in n-heptane, toluene, and anisole.     

Crystal structures and phase transformation of deuterated lithium imide, Li2ND

Half-Heusler compounds of Sn-doped TiCoSb “TiCoSn_xSb_1−x (x = 0.0, 0.01, and 0.05)” were prepared and their thermoelectric properties were measured above room temperature. From the EDX analysis, all the samples have three phases: the TiCoSn_xSb_1−x, Co-rich, and Ti-rich phases. The values of the thermoelectric power increase with Sn doping, and a positive thermoelectric power is obtained in the sample of TiCoSn_0.05Sb_0.95. The thermal conductivity decreases both with increasing temperature and with Sn content. The maximum value of ZT for p-type material is 0.030 at 988 K in the sample of TiCoSn_0.05Sb_0.95.     

一种基于高斯混合模型的轨迹预测算法

在智能交通控制系统、军事数字化战场、辅助驾驶系统中,实时、精确、可靠的移动对象不确定性轨迹预测具有极高的应用价值.智能轨迹预测不仅可以提供精准的基于位置的服务,而且可以提前监测和预判交通状况,进而推荐最佳路线,已经成为移动对象数据库研究的热点,亟需设计准确而高效的位置预测方法.针对现有方法的不足,提出了基于高斯混合模型的轨迹预测方法GMTP,主要步骤包括:(1) 针对复杂运动模式利用高斯混合模型建模;(2) 利用高斯混合模型计算不同运动模式的概率分布,进而将轨迹数据划分为不同分量;(3) 利用高斯过程回归预测移动对象最可能的运动轨迹.GMTP是高斯非线性概率统计模型,其优势在于:计算结果不仅是位置预测值,更是关于移动对象未来所有可能运动轨迹的概率分布,可以利用概率统计分布特性获得某种运动模式(如匀加速运动)下的位置预测.大量真实轨迹数据集上的实验结果表明:与相同参数设置下的高斯回归预测和卡尔曼滤波预测法相比,GMTP的预测准确性平均提高了22.2%和23.8%,预测时间平均缩减了92.7%和95.9%.     

Scalable digital hardware for a trapped ion quantum computer

Quantum Information Processing - Many of the challenges of scaling quantum computer hardware lie at the interface between the qubits and the classical control signals used to manipulate them....