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1.
《International Journal of Hydrogen Energy》2022,47(100):41956-41973
Due to stringent environmental regulations and the limited resources of fossil-based fuels, there is an urgent demand for clean and eco-friendly energy conversion devices. These criteria appear to be met by hydrogen proton exchange membrane fuel cells (PEMFCs). PEMFCs have attracted tremendous attention on account of their excellent performance with tunable operability and good portability. Nonetheless, their practical applications are hugely influenced by the scarcity and high cost of platinum (Pt) used as electrocatalysts at both cathode and anode. Pt is also susceptible to easy catalyst poisoning. Herein, this paper reviews the progress of the research regarding the development of electrocatalysts practically used in hydrogen PEMFCs, where the corner-stone reactions are cathodic oxygen reduction reaction (ORR) and anodic hydrogen oxidation reaction (HOR). To reduce the costs of PEMFCs, lessening or eliminating the use of Pt is of prime importance. For current and forthcoming laboratory/large-scale PEMFCs, there is much interest in developing substitute catalysts based on cheaper materials. As such are non-platinum (non-Pt), non-platinum group metals (non-PGMs), metal oxides, and non-metal electrocatalysts. Hence, high-performance, state-of-the-art, and novel structured electrocatalysts as replacements for Pt are needed. 相似文献
2.
Eivazzadeh-Keihan Reza Noruzi Ehsan Bahojb Mehrban Sarah Fattahi Aliabadi Hooman Aghamirza Moghim Karimi Meghdad Mohammadi Adibeh Maleki Ali Mahdavi Mohammad Larijani Bagher Shalan Ahmed Esmail 《Journal of Materials Science》2022,57(6):3855-3891
Journal of Materials Science - Chitosan is one of the natural cationic polymers with unique properties such as non-toxicity, biodegradability, biocompatibility, environmentally friendly that has... 相似文献
3.
《Ceramics International》2022,48(14):19818-19823
The aim of the present study was to examine the anti-coking and anti-carburizing behavior of amorphous AlPO4 coating. So, aluminum phosphate composition was synthesized by sol-gel process and applied on the AISI 304 stainless steel by dip coating technique. Anti-coking performance was examined in a tube furnace at 1000 °C for 30 min under Ethane (C2H6) atmosphere. Carburizing test was performed in a sealed charcoal medium at 1100 °C for a total of 30 h exposure time. Phase composition of the samples was analyzed by X-Ray Diffraction (XRD) after coking and carburizing tests. Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy (EDS) were employed to study the morphology and elemental analysis of the samples after coke and carbon formation experiments. Microhardness indenter was applied on the cross section of the carbon-exposed specimens to plot the hardness profile through the carburizing zone. The results of the coking experiment revealed catalytic coke formed on the uncoated surface, while irregular spherical coke with no trace of catalytic coke was formed on the coated surface, indicating the great anti-coking performance of the amorphous AlPO4 coating. The results of pack-carburizing test demonstrated that the thickness of the carbide layer formed on the bare surface was ~10 times greater than that of the coated sample. Hardness measurement for the amorphous AlPO4 coated sample detected lower values compared to those for the uncoated one at all distances from the surface, indicating less carbon diffusion occurred beneath the coated surface. In overall, the results declared that the amorphous AlPO4 coating could be a good candidate for surface protection of stainless steel against catalytic coke formation and carbon diffusion. 相似文献
4.
5.
《International Journal of Hydrogen Energy》2022,47(75):32031-32038
The activity of catalysts with various sizes was compared in a fixed-bed Fischer–Tropsch reactor under similar operating conditions by determining the deactivation model. Catalyst size had no impact on the type of deactivation model. The smaller catalyst showed a smaller deactivation constant of catalyst (kd) and a lower deactivation rate in the initial stage. The decline in the activities of the catalyst with a mesh size of 40 was lower than the other catalysts, suggesting its higher long-term stability (ass). Larger catalyst sizes led to the fouling of carbon and heavy hydrocarbons, decreasing the specific surface of the catalyst, thus increasing the pore diffusion resistance and further decrementing the catalyst activities. 相似文献
6.
Machine learning algorithms have been widely used in mine fault diagnosis. The correct selection of the suitable algorithms is the key factor that affects the fault diagnosis. However, the impact of machine learning algorithms on the prediction performance of mine fault diagnosis models has not been fully evaluated. In this study, the windage alteration faults (WAFs) diagnosis models, which are based on K-nearest neighbor algorithm (KNN), multi-layer perceptron (MLP), support vector machine (SVM), and decision tree (DT), are constructed. Furthermore, the applicability of these four algorithms in the WAFs diagnosis is explored by a T-type ventilation network simulation experiment and the field empirical application research of Jinchuan No. 2 mine. The accuracy of the fault location diagnosis for the four models in both networks was 100%. In the simulation experiment, the mean absolute percentage error (MAPE) between the predicted values and the real values of the fault volume of the four models was 0.59%, 97.26%, 123.61%, and 8.78%, respectively. The MAPE for the field empirical application was 3.94%, 52.40%, 25.25%, and 7.15%, respectively. The results of the comprehensive evaluation of the fault location and fault volume diagnosis tests showed that the KNN model is the most suitable algorithm for the WAFs diagnosis, whereas the prediction performance of the DT model was the second-best. This study realizes the intelligent diagnosis of WAFs, and provides technical support for the realization of intelligent ventilation. 相似文献
7.
Tourajizadeh Hami Yousefzadeh Mahdi Khalaji Ali Keymasi Bamdad Mahdi 《International Journal of Control, Automation and Systems》2022,20(5):1671-1681
International Journal of Control, Automation and Systems - In this paper, a new controllable simulator is proposed and modeled by which, experimental tests of the aircraft’s models can be... 相似文献
8.
Shahla Imani Moghaddam Hoda Pasdar Reza Fazaeli Saeed Mortazavi Nik 《Ceramics International》2021,47(15):20917-20922
Ferrites are an important group of magnetic materials which are used as absorbers. The incorporation of ferrite and conducting polymer achieves great enhancement in microwave absorption properties. The nanocomposites of hexagonal ferrites embedded by conducting polymers such as polypyrrole, polyaniline and polythiophene (PTH) have been paid much attention. In the present study, strontium hexagonal ferrite doped by Zr and Zn with the final formula of SrFe12-x(ZrZn)0.5xO19 considering x = 0.9 and embedded by PTH was produced to achieve a nanocomposite with the highest microwave absorbing ability. In this study, after synthesis of SrFe12O19(ZrZn)0.5xO19 and PTH, the nanocomposite was prepared by in situ polymerization. Wrapping the ferrite particles and PTH chains could form nanocomposite properly, and therefore acceptable interactions were observable between SrFe12-x(ZrZn)0.5xO19ferrite particles and PTH polymer chains in the composites. Assessing the X-ray diffraction (XRD) patterns of SrFe12-x(ZrZn)0.5xO19, PTH, and PTH/SrFe12-x(ZrZn)0.5xO19 nanocomposite indicated that the PTH characteristic peak shifts slightly and its peak intensity reduces, which may be attribute to the coating of PTH polymer chains onto SrFe12-x(ZrZn)0.5xO19 particles. We revealed also lower magnetic properties in the obtained nanocomposite. The morphological assessment also suggested that PTH could effectively coat the SrFe12-x(ZrZn)0.5xO19 particles. The synergistic effect of SrFe12-x(ZrZn)0.5xO19 particle plus PTH leads to microwave absorption percentage higher than 95% by PTH/SrFe12-x(ZrZn)0.5xO19 nanocomposite. Overall, nanocomposite creating by coupling interaction between SrFe12-x(ZrZn)0.5xO19 particles (x = 0.9) and PTH can effectively lead to achieve the highest rate of absorption of electromagnetic waves. 相似文献
9.
Salehe Gomroki Zahra Yavari Ahmad Reza Abbasian Meissam Noroozifar 《International Journal of Applied Ceramic Technology》2021,18(6):2099-2110
The spongy nickel oxide (SNO) was synthesized the solution combustion method. The SNO was selected as a promoter to boost the catalytic activity of nanoraspberry-like palladium (NRPd) toward electrooxidation of five light fuels (LFs): methanol, ethanol, formaldehyde, formic acid, and ethylene glycol. The X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy, and field emission scanning electron microscope techniques were used for the materials characterization. In comparison with nonpromoted Pd, the NRPd-SNO electrocatalyst shown an excellent efficiency in parameters like the electrochemical active surface area and anti-CO poisoning behavior. The turnover data and the parameters, including reaction order, activation energy, and the coefficients of electron transfer and diffusion, were evaluated for the each process of LFs electrooxidation. The outcome for NRPd-SNO activity toward LFs electrooxidation was compared to some reported electrodes. The SNO increases the removal of intermediates created in the oxidation of LFs that can poison the surface of palladium catalyst. This is due to the presence of the lattice oxygens in SNO structure and Ni switching between its high and low valances. The compatibility of the adsorption process of LFs on the surface of the NRPd-SNO catalyst with different isotherms was determined by studying the Tafel polarization and calculating the surface coverage. 相似文献
10.
The olive oil extraction industry often uses unit-constructed processing lines lacking in the necessary efficiency and sustainability. The development of efficient processing lines is seen as crucial in obtaining higher product quality and extraction yields. In recent years, numerous researchers and companies have explored the possibilities of assistance from pulsed electric fields (PEF) technology as a mean of reducing processing time and increasing extraction yields from different food crops. The current article shows the application of PEF technology in olive oil extraction, and specifically it researches the results from application of PEF technology in a pilot plant of industrial-layout olive oil extraction process. The experimental methodology involves construction of a plant meeting specific functional and cost criteria, capable of delivering unipolar electric pulses with amplitude <10 kV, current <200 A and 3 kW maximum average power. The analyses then focalize on the assessment of the results from PEF assistance on oil extraction, particularly in terms of extractability from crop and enhancement of bioactive substances content. The proposed PEF unit was found to be easy to install within existing plants, flexible in control and capable of continuous operation. Operating at different pulse and power levels, the plant results in increased process efficiency and content of desirable substances. 相似文献