钢铁生产的水能关系分析

从钢铁生产过程中水资源使用时的能耗角度研究了钢铁联合企业的水能关系，提出了水能强度的概念来评价企业生产过程中水资源利用的节能水平，建立了钢铁企业的水能关系模型。以中国某大型钢铁联合企业为例，计算并分析了该企业的水能关系。该企业总的水能量为55 709 kW·h/h，重复用水水能量占整个钢铁企业全部水能量的82%，补水水能量占16%，排水水能量占1%；各工序中热轧工序占比最大，其次是炼铁、炼钢工序，冷轧、烧结和炼焦工序较低。该企业的吨钢水能强度为0.208 kW·h/m3，炼铁工序的水能强度最高，热轧、炼钢工序次之，烧结、冷轧和炼焦工序较低。最后，从钢铁生产过程水资源利用的角度得到节能的方向及措施。     

高效液相色谱-质谱联用法测定薏苡仁药材中黄曲霉毒素

目的建立高效液相色谱-质谱联用法(high performance liquid chromatography-masss pectrometer,HPLC-MS)测定薏苡仁中药饮片中黄曲霉毒素B_1、B_2、G_1、G_2的方法,并对比不同产地薏苡仁中黄曲霉毒素含量。方法样品经过免疫亲合柱处理后,采用HPLC-MS进行测定。分析柱为C18柱(50 mm×2.1 mm, 1.8μm),流动相为10 mmol/L醋酸铵溶液-甲醇溶液,梯度洗脱,流速为0.3 mL/min,柱温为25℃。结果黄曲霉毒素B_1在0.26～10.4ng/mL浓度范围内与峰面积值均呈现良好的线性关系(r~2=0.9995),平均加样回收率为75.4%～123.9%,黄曲霉毒素B2在0.0875～3.5 ng/mL浓度范围内与峰面积值均呈现良好的线性关系(r~2=0.9996),平均加样回收率为71.1%～124.2%,黄曲霉毒素G_1在0.295～11.89 ng/mL浓度范围内与峰面积值均呈现良好的线性关系(r~2=0.9995),平均加样回收率为78.9%～112.2%,黄曲霉毒素G2在0.1475～5.9 ng/mL浓度范围内与峰面积值均呈现良好的线性关系(r~2=0.9992),平均加样回收率为73.8%～123.9%。结论该方法准确、可靠、专属性强,通过精确化合物离子监测,可准确的测定薏苡仁中黄曲霉毒素含量。     

Elastic Properties and Stacking Fault Energies of Borides,Carbides and Nitrides from First-Principles Calculations

Owing to the excellent elastic properties and chemical stability, binary metal or light element borides, carbides and nitrides have been extensively applied as hard and low-compressible materials. Researchers are searching for harder materials all the time. Recently, the successful fabrication of nano-twinned cubic BN(Tian et al. Nature 493:385–388, 2013) and diamond(Huang et al. Nature 510:250–253, 2014) exhibiting superior properties than their twin-free counterparts allows an efficient way to be harder. From this point of view, the borides, carbides and nitrides may be stronger by introducing twins, whose formation tendency can be measured using stacking fault energies(SFEs). The lower the SFEs, the easier the formation of twins. In the present study, by means of first-principles calculations, we first calculated the fundamental elastic constants of forty-two borides, seventeen carbides and thirty-one nitrides, and their moduli, elastic anisotropy factors and bonding characters were accordingly derived. Then, the SFEs of the {111} 112 glide system of twenty-seven compounds with the space group F43 m or Fm3m were calculated. Based on the obtained elastic properties and SFEs, we find that(1) light element compounds usually exhibit superior elastic properties over the metal borides, carbides or nitrides;(2) the 5 d transitionmetal compounds(ReB_2, WB, OsC, RuC, WC, OsN_2, TaN and WN) possess comparable bulk modulus( B) with that of cBN( B = 363 GPa);(3) twins may form in ZrB, HfN, PtN, VN and ZrN, since their SFEs are lower or slightly higher than that of diamond(SFE = 277 mJ/m~2). Our work can be used as a valuable database to compare these compounds.     

Co-coating effect of GdPO4 and carbon on LiFePO4 cathode surface for lithium ion batteries

The electronic conductivity enhanced has been extensively studied and reported in lithium iron phosph-ate (LiFePO₄). However, only few existing literatures are available for researchers to enhance simultaneously the ion and electronic conductivity of LiFePO₄. Herein, we disclose that the LiFePO₄ is co-coated with novel GdPO₄ and Carbon via a hydrothermal-assisted solid-phase method, contributing to particle size and dispersibility. What surprising is that the ionic and electronic conductivity of the material is significantly enhanced, and the interfacial side reaction is effectively inhibited between the materials and the electrolytes. The diverse proportions of the mixed coating (LiFePO₄/C&xGdPO₄ (x = 0, 1 wt%, 2 wt%, 3 wt%, 4 wt%)) are synthesized compared with bare LiFePO₄. The experimental results suggest that LiFePO₄/C&0.03GdPO₄ exhibits the most excellent electrochemical performance. There is discharge capacity of 158, 148.8, 141.6, 134.9, 121.8, 104.9, and 86.7mAh/g at 0.1, 0.2, 0.5, 1, 2, 5, and 10 C rates, respectively.     

固体碳直接还原钢铁厂含锌固废的理论与实践

 钢铁厂内的含锌固废数量巨大，同时富含铁、碳等元素，是可循环再利用的二次资源。通过固体碳直接还原ZnO和FeO的热力学分析，发现在非标准状态下，ZnO的还原条件要优于FeO。为此，在实验室条件下设计了含锌固废在不同温度和时间下的还原试验，发现在还原温度为1 423 K、还原时间为15 min以上时，脱锌率可达到90%，而铁的金属化率需要在1 573 K时才能接近90%；在还原温度低于1 423 K时，还原时间对脱锌率的影响较大；在还原温度高于1 473 K时，还原温度对脱锌率影响较小，同时脱锌率可达到95%。这些结果对国内当前处理含锌固废主要工艺(回转窑、转底炉)的操作制度设置具有重要的参考价值，也为如何选择合理的工艺路线，以低投入、低运营成本实现含锌固废的再利用提供了理论依据。     

考虑关节角加速度约束的仿人机器人偏摆力矩控制方法

针对仿人机器人步行过程中存在的机器人关节角加速度约束影响控制性能的问题，提出一种考虑关节角加速度约束的仿人机器人偏摆力矩控制方法.该方法充分考虑了双臂在摆动过程中对偏摆力矩的影响，根据力矩平衡条件得到需要抵消的偏摆力矩的大小与方向，将偏摆力矩的控制问题转化为带约束条件的二次规划问题，并设计了一种在线变步长迭代算法计算得到优化后的双臂摆动轨迹.实验表明，该方法能有效抵消机器人步行中产生的偏摆力矩，避免控制过程中的"削峰"现象，有效提高机器人的步行稳定性.     

Rapid screening of DON contamination in whole wheat meals by Vis/NIR spectroscopy and computer vision coupling technology

This work intends to develop an online experimental system for screening of deoxynivalenol (DON) contamination in whole wheat meals by visible/near-infrared (Vis/NIR) spectroscopy and computer vision coupling technology. Spectral and image information of samples with various DON levels was collected at speed of 0.15 m s⁻¹ on a conveyor belt. The two-type data were then integrated and subjected to chemometric analysis. Discriminant analysis showed that samples could be classified by setting 1000 μg kg⁻¹ as the cut-off value. The best correct classified rate obtained in prediction was 93.55% based on fusion of spectral and image features, with reduced prediction uncertainty as compared to single feature. However, quantification of DON by quantitative analysis was not successful due to poor model performance. These results indicate that, although not accurate enough to provide conclusive result, this coupling technology could be adopted for rapid screening of DON contamination in cereals and feeds during processing.     

推土机低温适应性研究及应用

推土机在低温环境下使用,常出现发动机启动困难,传动、液压、电气系统故障率高等问题.为解决推土机低温环境下使用问题,通过分析影响推土机低温使用性能的因素,提出了提升推土机低温性能措施,并对相关措施进行了实际应用.应用结果证明了提升推土机低温性能措施的有效性,使推土机可以在低温环境下正常使用.