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1.
Guan-Qiang Wang Ming-Song Chen Hong-Bin Li Y.C.Lin Wei-Dong Zeng Yan-Yong Ma 《材料科学技术学报》2021,77(18):47-57
The uniform refinement mechanisms and methods of deformed mixed and coarse grains inside a solution-treatment Ni-based superalloy during two-stage annealing treatment have been investigated.The two-stage heat treatment experiments include an aging annealing treatment(AT)and a subsequent recrystallization annealing treatment(RT).The object of AT is to precipitate some δ phases and consume part of storage energy to inhibit the grain growth during RT,while the RT is to refine mixed and coarse grains by recrystallization.It can be found that the recrystallization grains will quickly grow up to a large size when the AT time is too low or the RT temperature is too high,while the deformed coarse grains cannot be eliminated when the AT time is too long or the RT temperature is too low.In addition,the mixed microstructure composed of some abnormal coarse recrystallization grains(ACRGs)and a large number of fine grains can be observed in the annealed specimen when the AT time is 3 h and RT tem-perature is 980℃.The phenomenon attributes to the uneven distribution of δ phase resulted from the heterogeneous deformation energy when the AT time is too short.In the regions with a large number of δ phases,the recrystallization nucleation rate is promoted and the growth of grains is limited,which results in fine grains.However,in the regions with few δ phases,the recrystallization grains around grain boundaries can easily grow up,and the new recrystallization nucleus is difficult to form inside grain,which leads to ACRGs.Thus,in order to obtain uniform and fine annealed microstructure,it is a prereq-uisite to precipitate even-distributed δ phase by choosing a suitable AT time,such as 12 h.Moreover,a relative high RT temperature is also needed to promote the recrystallization nucleation around δ phase.The optimal annealing parameters range for uniformly refining mixed crystal can be summarized as:900℃×12 h+990℃×(40-60 min)and 900℃×12 h+1000℃×(10-15 min). 相似文献
2.
目的建立超高效液相色谱-串联质谱法同时测定糕点中6种常用合成甜味剂的分析方法。方法选用超纯水作为提取溶剂,涡旋和超声提取后,低温离心,取部分上清液加入正己烷除脂,Waters Atlantis■T3色谱柱、甲醇-5 mmol/L甲酸铵(含0.1%甲酸)作为流动相、亲水亲脂平衡型固相萃取柱HLB(hydrophile-lipophile balance)净化。结果6种甜味剂在质量浓度为10~200 ng/mL的曲线范围内呈良好线性关系,相关系数r均大于0.999,平均加标回收率在85.0%-98.2%之间,相对平均偏差(relative standard deviation,RSD)为1.3%~6.7%。结论该方法具有前处理简单、灵敏度高、检测速度快等优点,适合糖精钠、甜蜜素、三氯蔗糖、阿斯巴甜、阿力甜、纽甜的检测,但不适用于安赛蜜的检测。 相似文献
3.
Zhao Li Yahong Yuan Tianli Yue Jianghong Meng 《International Journal of Food Science & Technology》2019,54(9):2679-2689
5-HMF (5-hydroxymethyl-furfural) is a product of thermal treatment and is increasingly considered a food contaminant. Here, different concentrations of 5-HMF were measured in apple juice to evaluate the performance of the electronic nose (EN) and electronic tongue (ET) as rapid detection techniques for 5-HMF when coupled with chemometric analysis. Principal component analysis (PCA) and linear discriminant analysis (LDA) evaluated the discrimination capacity of EN and ET for 5-HMF. Loading analysis examined the discrimination contribution of the EN sensors. Partial least square (PLS) regression analysis established a quantitative prediction model for different concentrations of 5-HMF based on EN and ET data set. The optimal models had a coefficient of determination (R2) of 0.926 and a root-mean-square error of prediction (RMSEP) of 0.4168 in EN; there were R2 of 0.914 and RMSEP of 0.5836 in ET. These results demonstrate that EN and ET coupled with chemometric analysis are two promising approaches for the rapid and online detection of 5-HMF in apple juice. 相似文献
4.
Junyu Chen Yuze Li Yuming Jiang Liucheng Mao Mi Lai Lixia Jiang Huihui Liu Zongxiu Nie 《Advanced functional materials》2021,31(52):2106743
Cancer remains an intractable medical problem. Rapid diagnosis and identification of cancer are critical to differentiate it from nonmalignant diseases. High-throughput biofluid metabolic analysis has potential for cancer diagnosis. Nevertheless, the present metabolite analysis method does not meet the demand for high-throughput screening of diseases. Herein, a high-throughput, cost-effective, and noninvasive urine metabolic profiling method based on TiO2/MXene-assisted laser desorption/ionization mass spectrometry (LDI-MS) is presented for the efficient screening of bladder cancer (BC) and nonmalignant urinary disease. Combined with machine learning, TiO2/MXene-assisted LDI-MS enables high diagnostic accuracy (96.8%) for the classification of patient groups (including 47 BC and 46 ureteral calculus (UC) patients) from healthy controls (113 cases). In addition, BC patients can also be identified from noncancerous UC individuals with an accuracy of 88.3% in the independent test cohort. Furthermore, metabolite variations between BC and UC individuals are investigated based on relative quantification, and related pathways are also discussed. These results suggest that this method, based on urine metabolic patterns, provides a potential tool for rapidly distinguishing urinary diseases and it may pave the way for precision medicine. 相似文献
5.
6.
Yaseen K.R. Shariff Harish K. Choudhary Vijay Khopkar Ankit Yadav R. Madhusudhana Balaram Sahoo 《Ceramics International》2021,47(10):14907-14912
We report the mechanism involved in sol-gel auto-combustion synthesis of Ba–Sr-hexaferrite (Ba1-xSrxFe12O19; x = 0, 0.25, 0.5, 0.75 and 1, BSFO) ceramic powders through the analysis of the phases evolved during annealing of the as-synthesized powders, along with their structure and morphological studies. The XRD patterns of the as-synthesized samples indicate the formation of barium/strontium monoferrite ((Ba/Sr)Fe2O4) and maghemite (γ-Fe2O3) phases along with a minute amount of hematite (α-Fe2O3) phase. Annealing of these samples facilitates formation of BSFO phase through the solid state reaction between BaFe2O4 and γ-Fe2O3 phase. Interestingly, after annealing the samples with x = 0, 0.5 and 1, at 1000 °C for 2 h, we observed that phase pure Ba–Sr hexaferrite structure forms, but for samples with x = 0.25 and 0.75, high amount of hematite (α-Fe2O3) phase is observed, especially for x = 0.75. The reason associated with this could be the large difference between the ionic radii of Ba2+ and Sr2+ ions occupying the oxygen site. Furthermore, our study on annealing dependent phase evolution confirms that, this difference in ionic radii forbids the formation of a single phase Ba–Sr hexaferrite. The growth of clear hexagonal-shaped plate-like particles with varied particle sizes was observed for all the samples. The particle size variation may be due to the influence of the ionic radii difference on the sinterability of the samples. Our study provides a better understanding of synthesis mechanism of Ba–Sr hexaferrite samples. 相似文献
7.
《Ceramics International》2022,48(21):31265-31272
Bismuth layer structured Na0.5Bi4.5Ti4O15 (NBT) ferroelectric is one of the most promising materials for potential applications at high temperature. However, it is challenged to achieve a balance between high Curie temperature piezoelectric coefficient and excellent thermal stability for NBT piezoceramics. Here, through chemical modification at the A site of NBT with Ca2+, novel (Na0.5Bi0.5)1-xCaxBi4Ti4O15 piezoceramics with excellent properties fabricated by solid state reaction were studied. After doping of Ca2+, the Curie temperature TC increased from 648 °C to 662 °C while the piezoelectric coefficient d33 increased from 14 pC/N to 22 pC/N which can be attributed to the intrinsic contribution of TiO6 octahedral lattice distortion (tilting and rotation) and the extrinsic contribution of the increased density of domain walls. The composition of (Na0.5Bi0.5)0.95Ca0.05Bi4Ti4O15 ceramics with x = 0.05 has the optimal performance with high TC of 655 °C, large d33 of 22 pC/N, high electrical resistivity ρ close to 107 Ω cm at 500 °C and especially excellent thermal stability of d33 only about 5% reduction after being annealed at 625 °C. The work effectively reveals the great potential of CNBT-5 ceramics for high-temperature piezoelectric applications. 相似文献
8.
针对城际列车开行方案没有有效匹配城市轨道交通运能的问题,提出一种考虑区域协调性的城际列车开行方案优化方法。首先,以旅客出行费用最小和铁路运输效益最大为优化目标,考虑城际列车载客能力、出发地目的地(Original Destination,OD)客流需求和通过能力等约束;然后,在此基础上增加运能匹配度的限制,构建了考虑区域协调性的城际列车开行方案多目标非线性规划模型,并设计改进的模拟退火算法求解模型;最后,以广深城际铁路为例并进行两组对比分析。实验结果表明:考虑区域协调性的列车开行方案可以使旅客出行总广义费用降低约4.06%,铁路部门的效益提高约9.58%,旅客和铁路的系统总成本降低约23.27%;与遗传算法相比,改进的模拟退火算法在求解质量与收敛速度上均有较大提高。所提模型和算法可充分兼顾旅客和铁路双方利益,能够为城际列车开行方案优化问题提供有效解决方法。 相似文献
9.
为研究不同退火温度下高强IF钢的组织性能及织构的变化规律,采用温箱式电阻炉加热模拟罩式退火工艺,研究了不同退火温度下高强IF钢210P1冷轧板力学性能;对不同退火温度钢板的r90进行了统计并对其进行显微组织观察;采用X射线衍射仪及热场发射扫描电镜对不同退火温度的罩式退火成品板进行了织构分析。结果表明,在高强IF钢210P1冷轧板的罩式退火过程中,提高退火温度将使晶粒明显长大。随着退火温度的升高,屈服强度及抗拉强度下降,伸长率升高,n值略有上升,板材横向r值增加较明显,有利织构{111}取向密度增加,不利织构{100}取向密度降低。 相似文献
10.
摘要:为了进一步提高冷轧双相钢DP980的强塑性,采用低C-Si-Mn-Nb-Cr成分,通过调整连续退火工艺参数,系统研究了工艺组织性能的关系,利用OM、SEM、EBSD分析了不同退火温度条件下各相的比例、尺寸、形貌、分布,同时利用力学拉伸试验手段研究了连退两相区退火温度对强塑性的影响。结果表明,通过优化调整连续退火工艺,不仅可以在冷轧铁素体和马氏体双相钢的组织上获得少量的残余奥氏体,也能细化再结晶晶粒,最终获得ReL/Rm≤0.5、高伸长率A50≥15%的冷轧DP980,提高强塑性的同时改善了成型性能。 相似文献