Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

矿用履带式运输车在复杂开采条件下的应用

为了方便煤炭的运输，某矿使用了矿用履带式搬运车。履带运输车解决了轮式运输车在恶劣道路条件下不能行走的问题，这种履带车是一种新型的运输工具，其特点是体积小、转弯灵活、动力强大，可在不受场地限制的情况下轻松通过狭窄的地方，能有效解决山区、土壤、陡坡等恶劣条件下物料的运输问题，适合普通运输车辆无法通行的地方。介绍了矿用履带式搬运车的主要结构以及工作原理，并给出了实际应用中应注意的事项。     

一种植物油中苯并（a）芘含量测定的固相萃取前处理方法

为了建立一种准确性高、成本低的植物油中苯并(a)芘测定的样品前处理方法，基于GB 5009.7—2016以自制氧化铝柱为固相萃取柱，采用单因素试验对称样量、洗脱剂量、洗脱流速、吸附剂存放时间、吸附剂量这5个影响植物油中苯并（a）芘洗脱的因素进行研究，优化前处理条件，并对测定方法进行考察。结果表明：优化的前处理条件为称样量0.100 0 g、洗脱剂量120 mL、吸附剂（氧化铝）量22 g、洗脱流速1滴/2 s、吸附剂存放时间少于12周；方法检出限为0.2 μg/L，样品加标回收率为94.23%～100.00%，RSD为1.20%～7.36%；同一样品测定结果与SGS测定值接近，相对平均偏差为2.36%～3.50%。说明本试验方法测定结果准确，可应用于油脂企业植物油中痕量苯并（a）芘的测定。     

Braking behaviours of C/C–SiC mated with iron/copper-based PM in dry,wet and salt fog conditions

C/C–SiC composites have enormous potential as a new generation of brake materials. It is worth studying the friction and wear behaviours of these materials in special environments to ensure the safe and effective braking of trains in practical applications. In this study, the braking behaviours and wear mechanisms of C/C–SiC mating with iron/copper-based PM in dry, wet and salt fog conditions are compared in detail. The results show that the coefficient of friction (COF) in the wet condition is reduced by 14.13% compared with that under the dry condition. The COF value of the first braking under salt fog condition is increased by 12.27% and 30.75% compared to the dry and wet conditions, respectively. Additionally, the tail warping phenomenon of the braking curve disappears in wet condition, which is attributed to the weak adhesion of friction interfaces and the lubrication of the water film. The main wear mechanisms of C/C–SiC mating with iron/copper-based PM under dry condition are adhesive, fatigue and oxidation wear. However, the dominant wear in wet condition is abrasive wear. The cooling and lubrication of water reduce the tendency of thermal stress, and weaken adhesive and fatigue wear. Furthermore, salt fog can accelerate the corrosion of alloy friction film, leading to the damage of friction film. Meanwhile, the third body particles formed in salt fog condition participate in the braking process. The wear mechanisms in salt fog condition are dominated by abrasive and delamination wear.     

Synthesis and characterization of SrFeOx hetero-film resistance-switching device with low operation voltage

As a critical topological phase transition material, SrFeO_x could play an essential role in the field of resistive memory. How to implement resistance-switching more softly and ensure the stability of materials has always been a relevant research hotspot. Regulating the oxygen environment during the deposition process of the films can effectively control the stoichiometry of the functional layer and then improve the resistance-switching characteristics of the device. In this paper, a SrFeO_x hetero-film was prepared by oxygen pretreatment on the SrRuO₃ surface before SrFeO_x deposition, and the as-assembled micrometer-scale device exhibits a low set operating voltage of 0.6 V and favorable cycling characteristics. The SrFeO_x hetero-film reveals a vertical brownmillerite superlattice-like structure with ～20 nm perovskite buffer layer, which benefits the connection and rupture of conductive filament. Additionally, XPS and UV–vis were used to analyze the bonding energy and band gap of SrFeO_x hetero-film, and offers the experimental basis for the explanation of the conductive mechanism. Therefore, the device based on SrFeO_x hetero-film with low operation voltage provides a reference for low power consumption research on topological phase transition material.     

碱铝硅酸盐玻璃化学强化关键影响因素概述

化学强化是一种玻璃机械强度增强方法,适用于异型、超薄、高碱、高膨胀玻璃增强,因新型超薄显示产品的屏幕保护玻璃发展需要,化学强化技术重新在碱铝硅酸盐玻璃品种掀起研究热潮。本文对化学强化本质及铝硅酸盐玻璃在屏幕保护玻璃应用进行了回顾,基于玻璃化学强化的高CS、DOL和低CT诉求,归纳总结了关键影响因素,第1,碱铝硅酸盐玻璃的成分及结构是基础,氧化铝有利玻璃网络孔隙增大创造交换通道,氧化钠或氧化锂是离子交换关键物质;第2,对于玻璃组成和结构设计,要求玻璃网络键合度R=O/Si或O/(Si+Al)满足2.15~2.40,碱金属氧化物质量分数大于13%且膨胀系数大于6×10^-6/℃;第3,在化学强化工艺方面,化学强化温度决定离子扩散系数,化学强化时间决定DOL,一步法仅能获得相对较大的CS,而DOL不很理想,只有两种离子参与交换的二步法才有利于CS和DOL同步提高。     

非平稳条件下基于贝叶斯网络的内涝风险评估和管理方法

受非平稳条件因素(如气候变化、城市化)的影响,近几年内涝灾害频发。以Z市某地块为研究区域,借助地理信息系统(ArcGIS)和暴雨雨洪管理模型(SWMM)实现研究区排水管网的水动力模拟。在不同降雨情境下,比较分析现状系统及不同改造方案下的系统溢流量等信息,计算内涝风险指数。采用贝叶斯网络分析工具(Bayes Server)对引发内涝风险的主要因素进行推理、识别和分析,进而构建内涝风险评估模型。该模型便于决策者根据设计需求,结合各因素的不确定性范围和发生概率值,综合选取最适合的改造措施,优化市政排水防涝规划,为市政基础设施建设提供了依据。     

燃煤电厂软土层地基预处理方案和施工探究

本文阐述了预处理的重要性,揭示了当前施工中存在的问题,并对软土层地基处理提出了具体的方案。     

赵庄井田煤层气成藏条件研究

煤层气成藏条件研究是有效划分成藏类型或含气系统，煤层气富集高渗有利区预测、评价及优选的关键基础工作。基于赵庄井田煤层气地质条件及相关测试资料，借鉴前人研究成果，从煤生烃、煤层气储集和煤层气封盖保存条件等方面对赵庄井田煤层气成藏条件进行了研究。研究结果表明:煤中丰富的生烃物质在良好的生烃动力作用下，提高了生烃率和生烃量，为煤层气成藏提供了基础条件；煤变质程度高，促使煤中微小孔隙发育，煤层气储集能力增强和储集空间增大，有利于煤层气大量储存和富集；煤层埋深、围岩特性、构造及地下水径流等地质条件的有机匹配，为煤层气成藏提供了良好的封盖保存条件，是煤层气成藏的关键因素。     

废旧毛涤黏混纺面料脱色预处理工艺研究

以废旧毛涤黏混纺面料为研究对象,首先对面料进行清洁与消毒,然后对其组分进行定性、定量分析,最后通过单因素法优化,得出最佳的溶胀工艺为:m_(废旧面料)∶m_(DMSO)=1∶10,溶胀时间40 min,溶胀温度90℃。在该工艺下对织物进行溶胀处理,得到织物的质量损失率为3.06%,K/S值为16.906。