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以P123为模板剂,采用溶胶-凝胶法制备有序介孔SiO2,用N2吸附、扫描电镜及透射电镜对样品进行分析.结果表明,制备的介孔SiO2呈短棒状,具有有序柱状孔结构,平均孔径为5.75nm.有序介孔SiO2固化二元离子液体(1-甲基-丙基咪唑碘/1-甲基-己基咪唑碘)形成凝胶电解质.由于凝胶电解质中离子液体在介孔SiO2的孔道中有序排列,使凝胶电解质I3-的扩散系数增大,从而降低了电解质的内阻,抑制了染料敏化纳晶多孔膜-凝胶电解质界面的复合反应,使凝胶电解质染料敏化太阳电池具有较大的开路电压和填充因子,光电转换效率达到5.22%. 相似文献
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分别以SiO2、TiO2、Al2O3和ZnO等纳米氧化物为改性剂,采用流延法制得纳米氧化物/Nafion复合膜.XRD和ATR/FT-IR分析表明纳米氧化物在复合膜均匀分散,也没有发生团聚现象.对复合膜的质子传导和阻醇性能进行了测定,结果发现,纳米氧化物/Nafion复合膜具有较好的质子传导性能;阻醇性能均有较大幅度的提高,且以SiO2和TiO2改性的Nafion膜最为明显,甲醇透过系数分别从约10降低到约10-7和10-8数量级.这说明纳米氧化物/Nafion复合膜是一类较好的直接甲醇燃料电池用质子交换膜材料. 相似文献
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以非离子型表面活性剂P123和三甲基苯的微乳液为模板剂合成介孔SiO2粉体.以此粉体为原料,经干压成型、烧结制备多孔SiO2块材.分别用AlOOH溶胶和TiO2溶胶包覆多孔SiO2粉体,制成多孔SiO2/Al2O3块材和SiO2/TiO2块材.采用XRD、SEM、TEM、N2吸附法和阿基米德排水法对所制粉体和块材进行了表征,并研究了块材的热稳定性.结果表明,600~700℃烧结的多孔SiO2基块材的孔隙率为74%~76%.与多孔SiO2块材相比,在800~1000℃范围内,SiO2/Al2O3块材的热稳定性显著提高,SiO2/TiO2块材的热稳定性在800~900℃范围内有一定改善. 相似文献
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高温质子交换膜燃料电池用Nafion®/SiO2
复合膜研究进展 总被引:1,自引:0,他引:1
传统的质子交换膜燃料电池在高温下工作时,质子膜会因温度升高而发生脱水和膜电阻升高的现象,这对提高燃料电池的工作性能是一个致命的阻碍.由于Nafion(R)/SiO2复合膜具有较好的吸水和保水性能和较好的阻止甲醇渗透的能力,人们通过溶胶-凝胶法或重铸法合成了Nafion(R)/SiO2复合膜,并于高温(80~140℃)下应用在质子交换膜燃料电池和直接甲醇燃料电池中.简单介绍了Nafion(R)/SiO2复合膜的制备方法、结构性能及研究情况,并分析了存在的问题和其广阔的应用前景. 相似文献
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高温质子交换膜燃料电池用Nafion(R)/SiO2 复合膜研究进展 总被引:1,自引:0,他引:1
传统的质子交换膜燃料电池在高温下工作时,质子膜会因温度升高而发生脱水和膜电阻升高的现象,这对提高燃料电池的工作性能是一个致命的阻碍.由于Nafion(R)/SiO2复合膜具有较好的吸水和保水性能和较好的阻止甲醇渗透的能力,人们通过溶胶-凝胶法或重铸法合成了Nafion(R)/SiO2复合膜,并于高温(80~140℃)下应用在质子交换膜燃料电池和直接甲醇燃料电池中.简单介绍了Nafion(R)/SiO2复合膜的制备方法、结构性能及研究情况,并分析了存在的问题和其广阔的应用前景. 相似文献
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《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
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A four-ball tester was used to evaluate the anti-wear performance of three kinds of organomolybdemun compounds in the engine oils, i. e., molybdenum dialkyldithiophosphate (MoDDP), molybdenum dialkyldithiocarbamate ( MoDTC), and sulphur and phosphorus freeorganomolybdeum (Molybdate). The results indicate that a low concentration of MoDDP doesn' t improve the anti-wear properties of the commercial engine oils, but a high concentration of MoDDP can obviously improve the anti-wear properties and the load-carrying capacity of the engine oils. MoDTC doesn' t improve the antiwear properties of the engine oils, but worsens the anti-wear properties of the oils. Signifi can timprove ment of frictional and wear characteristics is obtained with Molybdate added in the commercial engine oils and the formulated oils. 相似文献
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Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
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A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
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The end of over unit products of more than Chinese firms have passed the quality grade certification for liquor products. These products involve distilled spirits beer wine yellow wine fruit syrup wine others cover over % of the national top-branded liquor products.…… 《中国标准化(英文版)》2008,25(1):30
The end of 2007, over 200 unit products of more than 80 Chinese firms have passed the quality grade certification for liquor products. These products involve distilled spirits, beer, wine, yellow wine, fruit syrup wine and others, and cover over 80% of the national top-branded liquor products.…… 相似文献
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Surface characterization and microstructure studies are performed on chemical vapor deposited (CVD) tungsten coating. There is about 2 μm thickness diffusion layer of tungsten in the molybdenum substrate. The thermal shock test shows tungsten coating has good adhesion with molybdenum substrate, but the elements of oxygen and carbon in the tungsten coating have the bad affection to the adhesion. The result of high-temperature diffusion experiment is the diffusion rate from molybdenum substrate to tungsten coating is faster. 相似文献
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On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
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N.A. Odintsova N.V. Ageenko K.V. Kiselev N.M. Sanina E.Y. Kostetsky 《International Journal of Refrigeration》2006,29(3):387
We studied a combined effect of the cryoprotectants both of lipid and carbohydrate origin at the presence of DMSO or without it on cell viability and the RNA synthesis in the embryonic mollusc and echinoderm cell cultures obtained at different developmental stages. Cryoprotective properties of exogenous lipids correlated with their thermotropic behavior. Lipid extracts from marine hydrobiontes, which thermal transitions are characterized by relatively small part of calorimetric thermogram area lying at temperatures above 0 °C (6–18%), were found to possess a considerable cryoprotective activity. The results are discussed in relation to the prediction of the cryoprotective activity of lipid extracts for marine animal cells. In addition, it was found that marine invertebrate cells can be cryopreserved without DMSO at the presence of trehalose and lipid extracts of some marine hydrobiontes. 相似文献
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David R. Smith F. R. Fickett 《Journal of research of the National Institute of Standards and Technology》1995,100(2):119-171
Pure silver is used extensively in the preparation of high-temperature superconductor wires, tapes, films, and other configurations in which the silver not only shields the superconducting material from the surrounding materials, but also provides a degree of flexibility and strain relief, as well as stabilization and low-resistance electrical contact. Silver is relatively expensive, but at this stage of superconductor development, its unique combination of properties seems to offer the only reasonable means of achieving usable lengths of conductor. In this role, the low-temperature physical (electrical, thermal, magnetic, optical) and mechanical properties of the silver all become important. Here we present a collection of properties data extracted from the cryogenic literature and, to the extent possible, selected for reliability. 相似文献