Si(001)斜切衬底上Ge量子点的固相外延生长

研究了Si(001)面偏[110]方向6°斜切衬底上Ge量子点的固相外延生长.实验结果表明,在Si(001)6°斜切衬底上固相外延生长Ge量子点的最佳退火温度为640℃,在斜切衬底上成岛生长的临界厚度低于在Si(001)衬底成岛生长的临界厚度,6°斜切衬底上淀积0.7nm Ge即可成岛,少于Si(001)衬底片上Ge成岛所需的淀积量.从Ge量子点的密度随固相外延温度的变化曲线,得到Ge量子点的激活能为1.9eV,远高于Si(111)面上固相外延Ge量子点的激活能0.3eV.实验亦发现,在Si(001)斜切衬底上固相外延生长的Ge量子点较Si(001)衬底上形成的量子点的热稳定性要好.     

多层Ge量子点的生长及其光学特性

用超高真空化学气相淀积系统在Si(1 0 0 )衬底上生长了多层Ge量子点.分别用TEM和AFM分析了埋层和最上层量子点的形貌和尺寸,研究了量子点层数和Si隔离层厚度对上层Ge量子点的形状和尺寸分布的影响.观察到样品的低温PL谱线有明显蓝移(87meV) ,Ge量子点的PL谱线的半高宽度(FWHM )为46meV ,说明采用UHV/CVD生长的多层量子点适合量子光电器件的应用     

多层Ge量子点的生长及其光学特性

用超高真空化学气相淀积系统在Si(100)衬底上生长了多层Ge量子点.分别用TEM和AFM分析了埋层和最上层量子点的形貌和尺寸,研究了量子点层数和Si隔离层厚度对上层Ge量子点的形状和尺寸分布的影响.观察到样品的低温PL谱线有明显蓝移(87meV),Ge量子点的PL谱线的半高宽度(FWHM)为46meV,说明采用UHV/CVD生长的多层量子点适合量子光电器件的应用.     

UHV/CVD法生长硅基低位错密度厚锗外延层

采用超高真空化学气相淀积系统,以高纯Si2 H6和GeH4作为生长气源,用低温缓冲层技术在Si(001)衬底上成功生长出厚的纯Ge外延层.对Si衬底上外延的纯Ge层用反射式高能电子衍射仪、原子力显微镜、X射线双晶衍射曲线和Ra-man谱进行了表征.结果表明在Si基上生长的约550nm厚的Ge外延层,表面粗糙度小于1nm,XRD双晶衍射曲线和Ra-man谱Ge-Ge模半高宽分别为530'和5.5cm-1,具有良好的结晶质量.位错腐蚀结果显示线位错密度小于5×105cm-2可用于制备Si基长波长集成光电探测器和Si基高速电子器件.     

UHV/CVD法生长硅基低位错密度厚锗外延层

采用超高真空化学气相淀积系统,以高纯Si2 H6和GeH4作为生长气源,用低温缓冲层技术在Si(001)衬底上成功生长出厚的纯Ge外延层.对Si衬底上外延的纯Ge层用反射式高能电子衍射仪、原子力显微镜、X射线双晶衍射曲线和Ra-man谱进行了表征.结果表明在Si基上生长的约550nm厚的Ge外延层,表面粗糙度小于1nm,XRD双晶衍射曲线和Ra-man谱Ge-Ge模半高宽分别为530'和5.5cm-1,具有良好的结晶质量.位错腐蚀结果显示线位错密度小于5×105cm-2可用于制备Si基长波长集成光电探测器和Si基高速电子器件.     

Ge/Si(100)量子点生长与形态分布的研究

利用超高真空化学气相淀积系统,通过控制淀积量、温度、流量等生长参数,在n型Si(100)衬底上自组装生长了一系列Ge量子点样品,用原子力显微镜进行了表征与分析.系统地研究了生长参数对Ge岛形态分布的影响并分析了有序、高密度Ge岛的生长机理.结果表明,从二维向三维岛跃迁后,最初形成的高宽比(高度与底宽的比值)在0.04～0.06之间的小岛是一种在低温下可以与圆顶岛共存的稳定岛,两种岛的分布随淀积参数的变化而变化.在高温下小岛几乎消失,流量的变化对小岛的密度影响较小.实验中获得小岛的密度最高为2.6×1010cm-2,圆顶岛的密度最高为4.2×109cm-2.     

Si1-xGex:C缓冲层上Ge薄膜的CVD外延生长

用化学气相沉积方法,在Si(100)衬底上生长Si1xGex:C合金作为缓冲层,继而外延生长了Ge晶体薄膜.根据AES测量结果可以认为,缓冲层包括由衬底中的Si原子扩散至表面与GeH4,C2H4反应而生成的Si1-xGex:C外延层和由Si1-xGex:C外延层中Ge原子向衬底方向扩散而形成的Si1-xGex层.缓冲层上外延所得Ge晶体薄膜晶体取向较为单一,其厚度超过在Si上直接外延Ge薄膜的临界厚度,且薄膜中的电子迁移率与同等掺杂浓度(1.0×1019 cm-3)的体Ge材料的电子迁移率相当.     

Si1-xGex:C缓冲层上Ge薄膜的CVD外延生长

用化学气相沉积方法,在Si(100)衬底上生长Si1xGex:C合金作为缓冲层,继而外延生长了Ge晶体薄膜.根据AES测量结果可以认为,缓冲层包括由衬底中的Si原子扩散至表面与GeH4,C2H4反应而生成的Si1-xGex:C外延层和由Si1-xGex:C外延层中Ge原子向衬底方向扩散而形成的Si1-xGex层.缓冲层上外延所得Ge晶体薄膜晶体取向较为单一,其厚度超过在Si上直接外延Ge薄膜的临界厚度,且薄膜中的电子迁移率与同等掺杂浓度(1.0×1019 cm-3)的体Ge材料的电子迁移率相当.     

Si1-xGex∶C缓冲层上Ge薄膜的CVD外延生长

用化学气相沉积方法，在Si(100)衬底上生长Si1-xGex∶C合金作为缓冲层，继而外延生长了Ge晶体薄膜. 根据AES测量结果可以认为，缓冲层包括由衬底中的Si原子扩散至表面与GeH4, C2H4反应而生成的Si1-xGex∶C外延层和由Si1-xGex∶C外延层中Ge原子向衬底方向扩散而形成的Si1-xGex层. 缓冲层上外延所得Ge晶体薄膜晶体取向较为单一，其厚度超过在Si上直接外延Ge薄膜的临界厚度，且薄膜中的电子迁移率与同等掺杂浓度(1.0E19cm-3)的体Ge材料的电子迁移率相当.     

硅基外延锗金属-半导体-金属光电探测器及其特性分析

利用超高真空化学汽相淀积(UHV/CVD)设备,以低温下生长的薄的Si1-xGex和Ge作为缓冲层,在Si(100)衬底上外延出表面平整(粗糙度＜1 nm)、位错密度低(＜5×105 cm-2、厚度约为500 nm的高质量纯Ge层.Ge层受到由于Si和Ge热膨胀系数不同引入的张应变,应变大小约为0.2%.以外延的Ge层为吸收区、在硅基上制备了台面面积为195×150 μm2的金属-半导体-金属(MSM)光电探测器.在-1 V偏压下,暗电流为2.4×10-7 A;在零偏压下,光响应波长范围扩展到1.6 μm以上.     

Preparation and Characterization of TaN ALD Precursors

High purity organic-tantalum precursors for thin film ALD TaN were synthesized and characterized.Vapor pressure and thermal stability of these precursors were studied.From the vapor pressure analysis,it was found that TBTEMT has a higher vapor pressure than any other published liquid TaN precursor,including TBTDET,TAITMATA,and IPTDET.Thermal stability of the alkyl groups on the precursors was investigated using a 1H NMR technique.The results indicated that the tertbutylimino group is the most stable group on TBTDET and TBTEMT as compared to the dialkylamido groups.Thermal stability of TaN precursors decreased in the following order:TBTDET ＞ PDMAT ＞ TBTEMT.In conclusion,precursor vapor pressure and thermal stability were tuned by making slight variations in the ligand sphere around the metal center.     

Curved crystal spectrometer for the measurement of X-ray lines from laser-produced plasmas

In order to diagnose the laser-produced plasmas, a focusing curved crystal spectrometer has been developed for measuring the X-ray lines radiated from a laser-produced plasmas. The design is based on the fact that the ray emitted from a source located at one focus of an ellipse will converge on the other focus by the reflection of the elliptical surface. The focal length and the eccentricity of the ellipse are 1350 mm and 0.9586, respectively. The spectrometer can be used to measure the X- ray lines in the wavelength range of 0.2-0.37 nm, and a LiF crystal （200） （2d = 0.4027 nm） is used as dispersive element covering Bragg angle from 30° to 67.5°. The spectrometer was tested on Shengnang- Ⅱ which can deliver laser energy of 60-80 J/pulse and the laser wavelength is 0.35 μm. Photographs of spectra including the 1 s2p ^1P1-1s^2 ^1S0 resonance line（w）, the 1s2p ^3P2-1s^2 1S0 magnetic quadrupole line（x）, the 1s2p ^3P1-1 s^2 ^1S0 intercombination lines（y）, the 1 s2p ^3S~1-1 s^2 ^1S0 forbidden line（z） in helium-like Ti Ⅹ Ⅺ and the 1 s2s2p ^2P3/2-1 s622s ^2S1/2 line（q） in lithium-like Ti Ⅹ Ⅹhave been recorded with a X-ray CCD camera. The experimental result shows that the wavelength resolution（λ/△ 2） is above 1000 and the elliptical crystal spectrometer is suitable for X-ray spectroscopy.     

Electronic Structure of Semiconductor Nanocrystals

This paper reviews our recent development of the use of the large-scale pseudopotential method to calculate the electronic structure of semiconductor nanocrystals, such as quantum dots and wires, which often contain tens of thousands of atoms. The calculated size-dependent exciton energies and absorption spectra of quantum dots and wires are in good agreement with experiments. We show that the electronic structure of a nanocrystal can be tuned not only by its size,but also by its shape. Finally,we show that defect properties in quantum dots can be significantly different from those in bulk semiconductors.     

Critical Stage Rule-Based Real Time Dispatch（RTD）System in Highly-Mixed-Products （HMP） FAB

An improving utilization and efficiency of critical equipments in semiconductor wafer fabrication facilities are concerned. Semiconductor manufacturing FAB is one of the most complicated and cost sensitive environments. A good dispatching tool will make big difference in equipment utilization and FAB output as a whole. The equipment in this paper is In-Line DUV Scanner. There are many factors impacting utilization and output on this equipment group. In HMP environment one of the issues is changing of reticule in this area and idle counts due to load unbalance between equipments. Here we'll introduce a rule-based RTD system which aiming at decreasing the number of recipe change and idle counts among a group of scanner equipment in a high-mixed-products FAB.     

GaAsSb/InAlAs PA DHBTs Grown by Production MBE

The epi material growth of GaAsSb based DHBTs with InAlAs emitters are investigated using a 4 × 100mm multi-wafer production Riber 49 MBE reactor fully equipped with real-time in-situ sensors including an absorption band edge spectroscope and an optical-based flux monitor. The state-of-the-art hole mobilities are obtained from 100nm thick carbon-doped GaAsSb. A Sb composition variation of less than ± 0.1 atomic percent across a 4 × 100mm platen configuration has been achieved. The large area InAlAs/GaAsSb/InP DHBT device demonstrates excellent DC characteristics,such as BVCEO＞6V and a DC current gain of 45 at 1kA/cm2 for an emitter size of 50μm × 50μm. The devices have a 40nm thick GaAsSb base with p-doping of 4. 5 × 1019cm-3 . Devices with an emitter size of 4μm × 30μm have a current gain variation less than 2% across the fully processed 100mm wafer. ft and fmax are over 50GHz,with a power efficiency of 50% ,which are comparable to standard power GaAs HBT results. These results demonstrate the potential application of GaAsSb/InP DHBT for power amplifiers and the feasibility of multi-wafer MBE for mass production of GaAsSb-based HBTs.     

Technology innovation and process integrations for sub-100nm gate patterning

This paper presents a brief overview of the Applied Centura(R)DPS(R)system,configured with silicon etch DPS Ⅱ chamber, with emphasis on discussing tuning capability for CD uniformity control. It also presents the studies of etch process chemistry and film integration impact for an overall successful gate patterning development. Discussions will focus on resolutions to key issues, such as CD uniformity, line-edge roughness, and multilayer film etching integration.     

White organic light-emitting devices based on fac tris（2- phenylpyridine） iridium sensitized 5,6,11,12-tetraphenylnap -hthacene

We have fabricated the white organic light-emitting devices （WOLEDs） based on 4,4＇ -bis（2,2 -diphenyl vinyl）-1,1＇ - biphenyl （DPVBi） and phosphorescence sensitized 5,6,11,12,-tetraphenylnaphthacene （rubrene）. The device structure is ITO/2T-NATA （20 nm）/NPBX （20 nm）/CBP： x%Ir（ppy）3：0.5% rubrene （8 nm）/NPBX （5 nm）/DPVBi （30 nm）/Alq（30 nm）/LiF（0.5 nm）/A1. In the devices, DPVBi acts as a blue light-emitting layer, the rubrene is sensitized by a phosphorescent material, fac tris （2-phenylpyridine） iridium [Ir（ppy）3], acts as a yellow light-emitting layer, and N,N＇ -bis- （1-naphthyl）- N,N＇ -diphenyl -1, 1＇ -biphenyl-4,4＇ -diamine （NPBX） acts as a hole transporting and exciton blocker layer, respectively. When the concentration of Ir （PPY）3 is 6wt%, the maximum luminance is 24960 cd/m^2 at an applied voltage of 15 V, and the maximum luminous efficiency is 5.17 cd/A at an applied voltage of 8 V.     

Complete approach to automatic identification and subpixel center location for ellipse feature

To meet the need of automatic image features extraction with high precision in visual inspection, a complete approach to automatic identification and sub-pixel center location for similar-ellipse feature is proposed. In the method, the feature area is identified automatically based on the edge attribute, and the sub-pixel center location is accomplished with the leastsquare algorithm. It shows that the method is valid, practical, and has high precision by experiment. Meanwhile this method can meet the need of instrumentation of visual inspection because of easy realization and without man-machine interaction.     

小角度扩展相关性近似算法分析

本论文提出一种在多天线MIMO信道相关性建模中小角度扩展近似理论算法,并应用于分析MIMO系统性能。分析中分别对三种不同角能量分布情况下的空间相关性研发快速近似计算法,并同时提出双模(Bi-Modal)角能量分布情况下的近似运算。通过分析这些新方法的近似效率,可以得到计算简单、复杂度低、而且符合实际的MIMO相关信道矩阵,对系统级的快速高效计算法的研究和系统级的评估以及误差分析具有重要的意义。     

Noise character analysis and the restraint of self-pulsation laser diodes

We calculate the Langevin noise sources of self-pulsation laser diodes, analyze the effects of active region noise and saturable-absorption region noise on the power fluctuation as well as period fluctuation, and propose a novel method to restrain the noise effects. A visible SIMULINK model is established to simulate the system, The results indicate that the effects of noise in absorption region can be ignored; that with the increase of DC injecting current, the noise effects enhance power jitter, and nevertheless, the period jitter is decreased; and that with external sinusoidal current modulating the self-pulsation laser diode, the noise-induced power jitter and period jitter can be suppressed greatly. This work is valuable for clock recovery in all-optical network.